One-Pot Synthesis of Biodiesel from Acid Oil Using a Switchable Solvent, 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU), as a Bifunctional Catalyst

نویسندگان

چکیده

Biodiesel is a promising alternative to petrodiesel, but its production from acid oils retains several technical challenges. Therefore, this study developed new approach involving 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-catalyzed one-pot reaction (simultaneous esterification-transesterification) produce biodiesel with enhanced efficiency. The was performed under water removal conditions and optimized using response surface methodology maximize the yield. optimal for had time of 2.73 h, temperature 143°C, methanol:oil molar ratio 24.3 : 1, DBU loading 30.1%. Under conditions, maximum total 97.1% obtained. could be repeatedly used at least 5 cycles yield over 91% biodiesel. This suggests that efficiently catalyzed esterification transesterification simultaneously DBU-catalyzed an efficient method high-free-fatty oils.

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ژورنال

عنوان ژورنال: International Journal of Energy Research

سال: 2023

ISSN: ['0363-907X', '1099-114X']

DOI: https://doi.org/10.1155/2023/2171897